New Technology Stores Solar Energy In The Form Of Carbon Monoxide.
Carbon dioxide is a gas that is necessary for to life on earth. Everytime we exhale we release carbon dioxide. It is a an important component of the air we breathe but only as a percentage of the other gases that make up the air we breath. However when any of the percentages of gases in our change dramatically it is cause for concern.
The chemical reaction that occurs during the combustion of any hydrocarbon, whether it is wood, grass, coal,natural gas or oil is also known as oxidation. Oxidation reactions always produce CO2 as byproduct. So with all of these sources of CO2 including ourselves, how can we hope to limit the amount the enters the air we breath? What to do with all of this CO2?
An international team of scientists led by Liang-shi Li at Indiana University has achieved a new milestone in the quest to recycle carbon dioxide in the Earth’s atmosphere into carbon-neutral fuels and others materials.
The chemists have engineered a molecule that uses light or electricity to convert the greenhouse gas carbon dioxide into carbon monoxide which is a carbon-neutral fuel source, more efficiently than any other method of “carbon reduction.”
An alternate version of the molecule, NGReCO2.
The process is reported in the Journal of the American Chemical Society.
“If you can create an efficient enough molecule for this reaction, it will produce energy that is free and storable in the form of fuels,” said Li, associate professor in the IU Bloomington College of Arts and Sciences’ Department of Chemistry.
This study is a major leap in that direction.
Burning fuel — such as carbon monoxide — produces carbon dioxide and releases energy. Turning carbon dioxide back into fuel requires at least the same amount of energy. A major goal among scientists has been decreasing the excess energy needed.
The study’s authors, from left, are Krishnan Raghavachari, Benjamin W. Noffke, Richard N. Schaugaard, Yijun Liu, Lu Liu and Liang-shi Li.
This is exactly what Li’s molecule achieves: requiring the least amount of energy reported thus far to drive the formation of carbon monoxide. The molecule is a nanographene-rhenium complex connected via an organic compound known as bipyridine, triggers a highly efficient reaction that converts carbon dioxide to carbon monoxide.
The ability to efficiently and exclusively create carbon monoxide is significant due to the molecule’s versatility.
“Carbon monoxide is an important raw material in a lot of industrial processes,” Li said.
It’s also a way to store energy as a carbon-neutral fuel since you’re not putting any more carbon back into the atmosphere than you already removed. You’re simply re-releasing the solar power you used to make it.
The secret to the molecule’s efficiency is nanographene — a nanometer-scale piece of graphite, a common form of carbon (i.e. the black “lead” in pencils) because the material’s dark color absorbs a large amount of sunlight.
Li said that bipyridine which are metal complexes have long been studied to reduce carbon dioxide to carbon monoxide with sunlight. But these molecules can use only a tiny sliver of the light in sunlight, primarily in the ultraviolet range, which is invisible to the naked eye. In contrast, the molecule developed at IU takes advantage of the light-absorbing power of nanographene to create a reaction that uses sunlight in the wavelength up to 600 nanometers which is a large portion of the visible light spectrum.
Essentially, Li said, the molecule acts as a two-part system: a nanographene “energy collector” that absorbs energy from sunlight and an atomic rhenium “engine” that produces carbon monoxide. The energy collector drives a flow of electrons to the rhenium atom, which repeatedly binds and converts the normally stable carbon dioxide to carbon monoxide.
The idea to link nanographene to the metal arose from Li’s earlier efforts to create a more efficient solar cell with the carbon-based material.
Next, Li plans to make the molecule more powerful, including making it last longer and survive in a non-liquid form, since solid catalysts are easier to use in the real world. He is also working to replace the rhenium atom in the molecule which is a rare element, with manganese, a more common and less expensive metal.
About the Research
All of the research on the study was conducted at IU. The first authors on the paper are Xiaoxiao Qiao and Qiqi Li, former graduate students at IU. Additional authors are professor Krishnan Raghavachari and graduate students Richard N. Schaugaard, Benjamin W. Noffke and Yijun Liu, all of the Department of Chemistry; Dongping Li, a visiting professor from Nanchang University; and Lu Liu, a visiting undergraduate from the University of Science and Technology of China.
This study was supported by IU Office of the Vice Provost for Research and the National Science Foundation.
About Gordon Smith Gordon's expertise in the area of industrial energy efficiency and alternative energy. He is an experienced electrical engineer with a Masters degree in Alternative Energy technology. He is the co-founder of several renewable energy media sites including Solar Thermal Magazine.