Owing to their unbeatable electro-optical properties and compatibility with existing silicon technology, silicon nanosheets (SiNSs) are one of most exciting recent discoveries. They have been the most promising candidate for use in various applications, such as in the process of manufacturing semiconductors and producing hydrogen.
In their study, published in the current edition of NPG Asia Materials, the research team reported an all-in-one strategy for the synthesis of high-purity SiNSs through the high-temperature molten salt (for example, NaCl)-induced exfoliation and simultaneous chemical reduction of natural clays.
According to the team, these newly synthesized silicon nanosheets are key components in the production of ever smaller electronic devices due to their ultrathin (thickness of ~5nm) body. Prof. Park states, “As the electrical and electronic devices are getting smaller and smaller, there is a great demand for manufacturing their individual componants to be nanoscale.” He continues, “Our new technique uses inexpensive natural clays and salt for preparing high-quality nanosheets, thereby cutting down production costs greatly.”
“Through the simultaneous molten-salt-induced exfoliation and chemical reduction of natural clay, both the salt and clay start to melt at a reaction temperature, ranging from 550°C to 700°C. The molten salt is, then, dissolved in the clay layers and disintegrated into individual nanosheets,” said Mr. Jaegeon Ryu, a doctoral researcher in Prof. Soojin Park’s lab and the first author of the study. He continues, “Using the metallothermic reduction, metallic oxides inside clays can be exchanged with silicon.”
The team reports that these nanosheets have a high surface area and contain mesoporous structures derived from the oxygen vacancies in the clay. They add, “These advantages make the nanosheets a highly suitable photocatalyst with an exceptionally high activity for the generation of hydrogen from a water-methanol mixture.”
This work has been supported by the Basic Science Research Program through the National Research Foundation (NRF) of Korea and has been funded by the Middle-Grade Researcher Supporting Program through the Korean Ministry of Science, ICT and Future Planning (MSIP).