Perovskite solar cells are the rising star in photovoltaics. They absorb light across almost all visible wavelengths, they have exceptional power conversion efficiencies exceeding 20% in the lab, and they are relatively easy to fabricate. So, why are perovskite solar cells yet to be found on the top of our roofs? One problem is their overall cost, and another is that cheaper perovskite solar cells have a short lifespan. A study published in Advanced Materials Interfaces by the Energy Materials and Surface Sciences Unit at the Okinawa Institute of Science and Technology Graduate University (OIST), reveals a cause for the short lifetime of perovskite solar cells with silver electrodes.
Currently, the most common electrode material in perovskite solar cells is gold, which is extremely expensive. A low-cost alternative to gold is silver, around 65 times cheaper. To keep the cost even lower, the team wants to use solution-processed method to fabricate the layers of the solar cell, instead of expensive vacuum-based techniques. The problem of using silver electrodes and the solution-based method is that silver gets corroded within days of the solar cell fabrication. The corrosion makes the electrode turn yellow, and reduces the efficiency of the cell. The OIST team, headed by Prof. Yabing Qi, has demonstrated the cause of this degradation and proposed an explanation.
In this study, the team analysed the composition of the corroded silver electrode and identified the formation of silver iodide as the reason for the electrode corrosion. The color change was due to the oxidation from silver to silver iodide. They also found that exposure to air accelerates the corrosion, when compared to dry nitrogen gas exposure.
The team proposed a mechanism for this damage: silver iodide forms because gas molecules from ambient air reach the perovskite material and degrade it forming iodine containing compounds. These iodine-containing compounds diffuse to the silver electrode and corrode it. The migration of both air molecules and iodine-containing compounds could happen through small pinholes present in the spiro-MeOTAD HTL layer (see animation). The pinholes present in the spiro-MeOTAD HTL layer produced with the solution-processed method were identified some months ago by Zafer Hawash, a PhD student in the same laboratory.
Replacing gold with silver and using the solution-processed method are key to bringing down the cost of the solar cells. The OIST team believes that understanding the corrosion mechanism is the first step in increasing the electrode lifetime. Since preventing the formation of pinholes in the spiro-MeOTAD HTL layer is essential for a longer cell lifetime, the team is also working on producing pinhole-free solar cells with the solution-process method, while the production of pinhole-free HTL with the vacuum-based method has already been published by the same group. “Perovskite-based solar cells show potential for commercial use as the next generation photovoltaic technology. Our goal is to design and fabricate large-area and low-cost photovoltaic modules with extended lifetime by employing appropriate HTLs and encapsulation materials,” explains Qi.