“We have opened the door to a new room,” says Professor Christof Wöll, Director of KIT Institute of Functional Interfaces (IFG). “This new application of metal-organic framework compounds is the beginning only. The end of this development line is far from being reached,” the physicist emphasizes.
Metal-organic frameworks, called MOFs for short, consist of two basic elements, metal node points and organic molecules, which are assembled to form microporous, crystalline materials. For about a decade, MOFs have been attracting considerable interest of researchers, because their functionality can be adjusted by varying the components. “A number of properties of the material can be changed,” Wöll explains.
The team of german research scientists at Karlsruher Institut Fur Technologie (KIT) have developed a metal-organic solar cell produced on the basis of a novel porphyrine-MOF is now presented by the researchers in the journal Angewandte Chemie (Applied Chemistry).
“The clou is that we just need a single organic molecule in the solar cell,” Wöll says. The researchers expect that the photovoltaic capacity of the material may be increased considerably in the future by filling the pores in the crystalline lattice structure with molecules that can release and take up electric charges.
By means of a process developed at KIT, the crystalline frameworks grow in layers on a transparent, conductive carrier surface and form a homogeneous thin film, so-called SURMOFs. “The SURMOF process is suited in principle for a continuous manufacturing process and also allows for the coating of larger plastic carrier surfaces,” Wöll says. Thanks to their mechanical properties, MOF thin films of a few hundred nanometers in thickness can be used for flexible solar cells or for the coating of clothing material or deformable components. While the demand for technical systems converting sunlight into electricity is increasing, organic materials represent a highly interesting alternative to silicon that has to be processed at high costs before it can be used for the photoactive layer of a solar cell.
Jinxuan Liu, Wencai Zhou, Jianxi Liu, Ian Howard, Goran Kilibarda, Sabine Schlabach, Damien Coupry, Matthew Addicoat, Satoru Yoneda, Yusuke Tsutsui, Tsuneaki Sakurai, Shu Seki, Zhengbang Wang, Peter Lindemann, Engelbert Redel, Thomas Heine, and Christof Wöll: Photoinduzierte Erzeugung von Ladungsträgern in epitaktischen MOF-Dünnschichten: hohe Leistung aufgrund einer indirekten elektronischen Bandlücke?, Angewandte Chemie, Ausgabe 25/2015. German edition: DOI: 10.1002/ange.201501862, International edition: DOI: 10.1002/anie.201501862
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This post was prepared by Solar Thermal Magazine staff.