Scientists Create Dual Purpose Film for Hydrogen Based Energy Storage

Scientists Create Dual Purpose Film for Hydrogen Based Energy Storage
Scientists Create Dual Purpose Film for Hydrogen Based Energy Storage

Developing Hydrogen Based Energy Storage.

Energy storage is the holy grail in the battle for dominance over fossil fuels. Sounds a little melodramatic but if we do not find a way to move to 100 percent renewable or clean energy, we will jeopardize our very existence here on earth. The planet will be fine, but probably it will be without us.

The warming of the oceans and melting of the glaciers is not something we will be able to recover from. So why is energy storage so important in this equation?

Simply put, the pathways that we currently have for affordable renewable energy are wind turbines and solar photo-voltaic technology. These are great source of clean electricity but they are by their very nature, intermittent. These cost effective technologies need to be implemented on a scale that allow us to over produce electricity when the sun is shining and the wind blowing. The way to harvest that is energy storage.

Researchers all over the world are working on energy storage in the form of batteries, super capacitors, fly-wheels, pumped storage and hydrogen for fuel cells.

Tesla who is know for electric cars and solar panels is now also one of the biggest producers of lithium-ion battery systems for residential and commercial systems.

Tesla who is know for electric cars and solar panels is now also one of the biggest producers of lithium-ion battery systems for residential and commercial systems. – Hydrogen based energy storage is another option.


Rice University scientists who want to gain an edge in energy production and storage report they have found it in molybdenum disulfide.

The Rice University lab of chemist James Tour has turned molybdenum disulfide’s two-dimensional form into a nanoporous film that can catalyze the production of hydrogen or be used for energy storage.

The versatile chemical compound classified as a dichalcogenide is inert along its flat sides, but previous studies determined the material’s edges are highly efficient catalysts for hydrogen evolution reaction (HER), a process used in fuel cells to pull hydrogen from water.

Tour and his colleagues have found a cost-effective way to create flexible films of the material that maximize the amount of exposed edge and have potential for a variety of energy-oriented applications.

The Rice University research appears in the journal Advanced Materials.

Molybdenum disulfide isn’t quite as flat as graphene, the atom-thick form of pure carbon, because it contains both molybdenum and sulfur atoms. When viewed from above, it looks like graphene, with rows of ordered hexagons. But seen from the side, three distinct layers are revealed, with sulfur atoms in their own planes above and below the molybdenum.

This crystal structure creates a more robust edge, and the more edge, the better for catalytic reactions or storage, Tour said.

“So much of chemistry occurs at the edges of materials,” he said.

A two-dimensional material is like a sheet of paper: a large plain with very little edge. But our material is highly porous. What we see in the images are short, 5- to 6-nanometer planes and a lot of edge, as though the material had bore holes drilled all the way through.

The new film was created by Tour and lead authors Yang Yang, a postdoctoral researcher; Huilong Fei, a graduate student; and their colleagues. It catalyzes the separation of hydrogen from water when exposed to a current.

Its performance as a HER generator is as good as any molybdenum disulfide structure that has ever been seen, and it’s really easy to make.

While other researchers have proposed arrays of molybdenum disulfide sheets standing on edge, the Rice group took a different approach. First, they grew a porous molybdenum oxide film onto a molybdenum substrate through room-temperature anodization, an electrochemical process with many uses but traditionally employed to thicken natural oxide layers on metals.

The film was then exposed to sulfur vapor at 300 degrees Celsius (572 degrees Fahrenheit) for one hour. This converted the material to molybdenum disulfide without damage to its nano-porous sponge-like structure, they reported.

A 3000 Farad supercapacitor

A 3000 Farad supercapacitor


 

The films can also serve as supercapacitors, which store energy quickly as static charge and release it in a burst. Though they don’t store as much energy as an electrochemical battery, they have long lifespans and are in wide use because they can deliver far more power than a battery.

The Rice lab built supercapacitors with the films; in tests, they retained 90 percent of their capacity after 10,000 charge-discharge cycles and 83 percent after 20,000 cycles.

“We see anodization as a route to materials for multiple platforms in the next generation of alternative energy devices,” Tour said.

These could be fuel cells, supercapacitors and batteries. And we’ve demonstrated two of those three are possible with this new material.

Co-authors of the paper are Rice graduate students Gedeng Ruan and Changsheng Xiang. Tour is the T.T. and W.F. Chao Chair in Chemistry as well as a professor of materials science and nanoengineering and of computer science.

The Peter M. and Ruth L. Nicholas Postdoctoral Fellowship of Rice’s Smalley Institute for Nanoscale Science and Technology and the Air Force Office of Scientific Research Multidisciplinary University Research program supported the research.

Read the abstract at http://onlinelibrary.wiley.com/doi/10.1002/adma.201402847/abstract

 

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